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Metallurgical Engineering · Q53

Iron Making in Metallurgy

Engineering and GATE · Metallurgical Engineering · question 53

Q53

Desulfurisation of hot metal is favoured by

A.
reducing and neutral slag
B.
high activity co-efficient of sulphur in metal
C.
oxidising and basic slag
D.
reducing and basic slag
Answer

Answer: Option D

Solution

Answer: Option D
Solution:
Desulfurisation is the process of removing sulphur from hot metal (usually molten iron) to improve its quality.

This process is favoured by a reducing atmosphere because an oxidising environment can lead to reversion of sulphur back into the metal.

A basic slag (rich in lime, CaO) reacts with sulphur to form calcium sulphide (CaS), which is stable and can be easily removed.

Thus, a reducing and basic slag environment promotes maximum sulphur removal by encouraging the formation and retention of CaS in the slag phase.

Therefore, Option D is the correct answer as it provides the most favourable conditions for desulfurisation.