Vidyalelo
Chemical Engineering · Q331

Petroleum Refinery Engineering

Engineering and GATE · Chemical Engineering · question 331

Q331

Pick out the wrong statement.

A.
Iso-paraffin crack faster than n-paraf-fin
B.
Catalytic cracking is endothermic, but the regeneration of catalyst is exothermic
C.
Rate of decomposition of olefins in catalytic cracking is slightly slower than the thermal cracking
Answer
D.
None of these

Answer: Option C

Solution

Answer: Option C
Solution:
The rate of decomposition of olefins in catalytic cracking is actually faster than in thermal cracking. This is because catalytic cracking provides a more efficient pathway with lower activation energy compared to thermal cracking. Catalysts accelerate the cracking process, leading to a higher rate of reaction for olefins.

Option A is incorrect because n-paraffins generally crack faster than iso-paraffins due to less stable intermediates.

Option B is correct as stated; catalytic cracking is indeed endothermic, requiring heat input, whereas the regeneration of the catalyst is exothermic, releasing heat.

Option D cannot be the answer since one of the previous statements is incorrect.