Tired and weary he returned home late that night.

Answer: Option A

Exhausted : very tired.
Frustrated : feeling or expressing distress and annoyance resulting from an inability to change or achieve something.
Lithe : (especially of a person's body) thin, supple, and graceful.
Emancipated : free from legal, social, or political restrictions; liberated.
Weary : feeling or showing extreme tiredness, especially as a result of excessive exertion.

Synonym of Weary is Exhausted