Sublimation temperature of dry ice (solid CO2 ) is __________ °C.
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The equation relating E, P, V and T which is true for all substanes under all conditions is given by ( ∂ V ∂ E ) T = T ⋅ ( ∂ T ∂ P ) H − P . This equation is called the
A. Maxwell's equation
B. Thermodynamic equation of state
C. Equation of state
D. Redlich-Kwong equation of state
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Henry's law is closely obeyed by a gas, when its __________ is extremely high.
A. Pressure
B. Solubility
C. Temperature
D. None of these
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If an ideal solution is formed by mixing two pure liquids in any proportion, then the __________ of mixing is zero.
A. Enthalpy
B. Volume
C. Both A & B
D. Neither A nor B
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The ammonia synthesis reaction represented by N2 + 3H2 ⇋ 2NH3 ; ΔH = -22.4 kcal, is
A. Endothermic
B. Exothermic
C. Isothermal
D. Adiabatic
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Free energy changes for two reaction mechanism 'X' and 'Y are respectively - 15 and - 5 units. It implies that X is
A. Slower than Y
B. Faster than Y
C. Three times slower than Y
D. Three times faster than Y
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Which of the following has the minimum value of COP for a given refrigeration effect?
A. Reverse Carnot cycle
B. Ordinary vapour-compression cycle
C. Vapour-compression process with a reversible expansion engine
D. Air refrigeration cycle
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No work is done by the system, when a reaction occurs at constant
A. Volume
B. Temperature
C. Pressure
D. None of these
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In the reaction, H2 + I 2 ⇋ 2HI , addition of an inert gas will
A. Increase the partial pressure of H2
B. Increase the partial pressure of I 2
C. Increase the total pressure and hence shift the equilibrium towards the right
D. Not effect the equilibrium conditions
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The work done in isothermal compression compared to that in adiabatic compression will be
A. Less
B. More
C. Same
D. More or less depending upon the extent of work done
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What happens in a reversible adiabatic expansion process?
A. Heating takes place
B. Cooling takes place
C. Pressure is constant
D. Temperature is constant
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Which of the following is affected by the temperature?
A. Fugacity
B. Activity co-efficient
C. Free energy
D. All of the above
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Which is an example of closed system?
A. Air compressor
B. Lquid cooling system of an automobile
C. Boiler
D. None of these
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Entropy of an ideal gas depends upon its
A. Pressure
B. Temperature
C. Both A & B
D. Neither A nor B
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At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by (where, μ = standard chemical potential at unit fugacity (f° = 1 atm.) and the gas behaves ideally.)
A. μ° + RT lnf
B. μ°+ R lnf
C. μ° + T lnf
D. μ° + T R lnf
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Partial molal quantities are important in the study of
A. Ideal gases
B. Ideal solutions
C. Non-ideal mixtures
D. A pure component
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For organic compounds, group contribution method can be used for the estimation of
A. Critical properties
B. Specific gravity
C. Specific volume
D. Thermal conductivity
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The efficiency of a Carnot heat engine operating between absolute temperatures T1 and T2 (when, T1 > T2 ) is given by T 1 T 1 − T 2 . The co-efficient of performance (C.O.P.) of a Carnot heat pump operating between T1 and T2 is given by
A. T 1 − T 2 T 1
B. T 1 − T 2 T 2
C. T 2 T 1
D. T 1 T 2
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Internal energy of an element at 1 atm and 25° C is __________ kcal/kg.mole.
A. 0
B. 273
C. 25
D. None of these
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At the critical point of a substance
A. The surface tension vanishes
B. Liquid and vapour have the same density
C. There is no distinction between liquid and vapour phases
D. All of the above
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