A pollutant P degrades according to first order kinetics. An aqueous stream containing P at 2 kmole/m3 and volumetric flow rate 1 m3/h requires a mixed flow reactor of volume V to bring down the pollutant level to 0.5 kmole/m3. The inlet concentration of the pollutant is now doubled and the volumetric flow rate is tripled. If the pollutant level is to be brought down to the same level of 0.5 kmole/m3, the volume of the mixed flow reactor should be increased by a factor of
The decomposition of A into B is represented by the exothermic reaction, A ⇋ 2B. To achieve maximum decomposition, it is desirable to carry out the reaction.
Pick out the wrong statement below:
I. For the same conversion, the holding time required in a batch reactor, is always equal to the space time required in a PFR.
II. Two mixed reactors of unequal size are available for producing a specified product, formed by a homogenous second order reaction. To achieve maximum production rate, the smaller reactor should be placed in series before the larger reactor.
III. Arrehenius equation describing the effect of temperature on rate constant is given by, K=A.e−RTEa
IV. The mechanism for the decomposition of CH3CHO into CH4 and CO in presence of I2 is:
CH3CHO + I2 → CH3I + HI + CO; slow
CH3I + HI → CH4 + I2; fast
Then the rate of disappearance CH3CHO is equal to K.CCH3l.CHl and acts as a catalyst.
A CSTR is to be designed in which an exothermic liquid phase first order reaction of the type, A → R, is taking place. The reactor is to be provided with a jacket in which coolant is flowing. Following data is given: CA0= 5 kmole/m3; XA = 0.5; Feed temperature = reactor temperature = 40°C. Rate constant at 40°C = 1 min-1; (ΔH) = -40 kJ/mole; ρ = 1000 kg/m3 CP = 4 J/gm.°C; q = 10-3 m3/min (ρ and CP are same for the reactant and product streams). The amount of heat to be removed is