In the mixture obtained by mixing 25.0 mL × 1.2 × 10-3 MMnCl2 and 35.0 mL of 6.0 × 10-4 M KCl solution, the concentration (M) of Mn2+ , K+ and CI- ions respectively are
A. 6.0 × 10-4 , 3.0 × 10-4 , 1.5 × 10-3
B. 6.0 × 10-4 , 3.0 × 10-4 , 9 × 10-4
C. 5.0 × 10-4 , 3.5 × 10-4 , 13.5 × 10-3
D. 5.0 × 10-4 , 3.5 × 10-4 , 8.5 × 10-4
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An aqueous solution containing m moles of non-volatile solute freezes at -0.186°C. The elevation in the boiling point of the same aqueous solution (Kf = 1.86°, Kb = 0.512°) would be
A. 0.186
B. 0.512
C. 0.0512
D. 0.51/1.86
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Among the following, the equilibrium which is not affected by an increase in pressure is
A. 2SO3 (g) ⇌ 2SO2 (g) + O2 (g)
B. H2 (g) + l2 (s) ⇌ 2HI(g)
C. C(s) + H2 O(g) ⇌ CO(g) + H2 (g)
D. 3Fe(s) + 4H2 O(g) ⇌ Fe3 O4 (s) + 4H2 (g)
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The number of degrees of freedom for a system consisting of NaCl(s), Na+ (aq) and Cl- (aq) at equilibrium is
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As per the kinetic theory of ideal gases, which of the following statements is not correct?
A. Gas particles have mass but no volume
B. Particles are in a Brownian motion between collisions
C. During the collision, the system does not lose energy
D. Particles exert same force per unit area on all sides of the container
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The number of degrees of freedom of a system consisting of solid sucrose in equilibrium with an aqueous solution of sucrose is
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For an ideal gas,
A. ( ∂ T ∂ p ) V ( ∂ V ∂ T ) p ( ∂ p ∂ V ) T = 0
B. ( ∂ T ∂ p ) V ( ∂ V ∂ T ) p ( ∂ p ∂ V ) T = − 1
C. ( ∂ T ∂ p ) V ( ∂ V ∂ T ) p ( ∂ p ∂ V ) T = + 1
D. ( ∂ T ∂ p ) V ( ∂ V ∂ T ) p ( ∂ p ∂ V ) T = + 2
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If a gas obeys equation of state p(V - nb) = nRT, the ratio ( C p − C V ) ideal ( C p − C V ) is
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The internal pressure of a van der Waals gas is
A. independent of the molar volume
B. inversely proportional to the molar volume
C. inversely proportional to square of the molar volume
D. directly proportional to the molar volume
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Under the equilibrium conditions for the reaction, C(s) + CO2 (g) ⇌ 2CO(g), the total pressure is 12 atm. The value of Kp is
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According to the Ehrenfest classification of phase transition the above diagram refers to
A. zeroth order phase transition
B. first order phase transition
C. second order phase transition
D. λ transition
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For 1 mol of a monoatomic ideal gas, the relation between pressure (p), volume (V) and average molecular kinetic energy ( ε ) is
A. p = V N A ε
B. p = 3 V N A ε
C. p = 3 V 2 N A ε
D. p = 2 V ε 2 N A
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For the pair of reactions given below,
(i) N2 (g) + 3H2 (g) ⇌ 2NH3 (g)
(ii) 2 1 N2 (g) + 2 3 H2 (g) ⇌ NH3 (g)
If at a particular temperature, Kp1 and Kp2 are the equilibrium constants for reactions (i) and (ii) respectively then
A. Kp1 = 2Kp2
B. Kp1 = K p2 2
C. 2Kp1 = Kp2
D. K p1 2 = Kp2
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The Bronsted acidity of boron hydrides follows the order
A. B2 H6 > B4 H10 > B5 H9 > B10 H14
B. B2 H6 = B4 H10 > B5 H9 = B10 H14
C. B10 H14 > B5 H9 > B4 H10 > B2 H6
D. B5 H9 > B4 H10 > B2 H6 > B10 H14
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The pH of buffer solution containing 4 × 10-3 and 0.4 moles of acetic acid (pKa = 4.76) and sodium acetate respectively will be
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The freezing point constant for water is 1.86 K (mol/kg)-1 . The freezing point when 0.01 mol glucose is added to 1 kg water is
A. 1.86 K
B. -1.86 K
C. 0.0186 K
D. -0.0186 K
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On the pressure-temperature diagram for a one-component system, the point where the solid-liquid and the liquid-gas curves intersect is
A. triple point
B. critical point
C. melting point
D. boiling point
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The triple point for water is
A. unique
B. depends on p but is independent of T
C. depends on T but is independent of p
D. depends on both p and T
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