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Chemical Engineering · Q511

Chemical Engineering Thermodynamics

Engineering and GATE · Chemical Engineering · question 511

Q511

For a reversible process involving only pressure-volume work

A.
(dF)T, P < 0
B.
(dF)T, P > 0
C.
(dF)T, P = 0
Answer
D.
(dA)T, V < 0

Answer: Option C

Solution

Answer: Option C
Solution:
Here the is Gibbs free energy and is Helmholtz free energy.
Since for an reversible process
For, constant temperature and constant pressure process the above equation can be written as

For reversible process.