The partial molar enthalpy of a component in an ideal binary gas mixture of composition Z, at a temperature T and pressure P, is a function only of
A. T
B. T and P
C. T, P and Z
D. T and Z
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Which of the following behaves most closely like an ideal gas?
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The internal energy of a gas obeying P (V - b) RT (where, b is a positive constant and has a constant Cv ), depends upon its
A. Pressure
B. Volume
C. Temperature
D. All of the above
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Gibbs free energy of mixing at constant pressure and temperature is always
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Heating of water under atmospheric pressure is an __________ process.
A. Isochoric
B. Isobaric
C. Adiabatic
D. Isothermal
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Partial molar free energy of an element A in solution is same as its
A. Chemical potential
B. Activity
C. Fugacity
D. Activity co-efficient
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The absolute entropy for all crystalline substances at absolute zero temperature is
A. Zero
B. Negative
C. More than zero
D. Indeterminate
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Equilibrium constant decreases as the temperature
A. Increases, for an exothermic reaction
B. Decreases, for an exothermic reaction
C. Increases, for an endothermic reaction
D. None of these
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A solid is transformed into vapour without going to the liquid phase at
A. Triple point
B. Boiling point
C. Below triple point
D. Always
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The number of degrees of freedom at the triple point of water is
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Specific __________ does not change during phase change at constant temperature and pressure.
A. Entropy
B. Gibbs energy
C. Internal energy
D. Enthalpy
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Tea kept in a thermos flask is vigorously shaken. If the tea is considered as a system, then its temperature will
A. Increase
B. Decrease
C. Remain unchanged
D. First fall and then rise
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Which of the following is an extensive property of a system?
A. Heat capacity
B. Molal heat capacity
C. Pressure
D. Concentration
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The expression for entropy change, ΔS = nCp .ln( T 1 T 2 ) , is valid for the __________ of a substance.
A. Simultaneous pressure & temperature change
B. Heating
C. Cooling
D. Both B and C
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When a system in equilibrium is subjected to a change in temperature, pressure or concentration, the equilibrium is displaced in a direction which tends to undo the effect of the change. This is called the
A. Le-Chatelier principle
B. Kopp's rule
C. Law of corresponding state
D. Arrehenius hypothesis
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Dryness fraction of wet steam is defined as the ratio of mass of vapour in the mixture to the mass of mixture __________ calorimeter is not used for measuring the dryness fraction of steam.
A. Bomb
B. Separating
C. Bucket
D. Throttling
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Steam undergoes isentropic expansion in a turbine from 5000 kPa and 400°C (entropy = 6.65 kJ/kg.K) to 150 kPa) (entropy of saturated liquid = 1.4336 kJ/kg.K, entropy of saturated vapour = 7.2234 kJ/kg.K) The exit condition of steam is
A. Superheated vapour
B. Partially condensed vapour with quality of 0.9
C. Saturated vapour
D. Partially condensed vapour with quality of 0.1
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The extensive properties are
A. Volume, mass and number of moles
B. Free energy, entropy and enthalpy
C. Both A and B
D. None of these
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The intensive properties are
A. Molar volume, density, viscosity and boiling point
B. Refractive index and surface tension
C. Both A and B
D. None of these
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Which of the following has the least thermal efficiency?
A. Steam engine
B. Carnot engine
C. Diesel engine
D. Otto engine
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