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Atomic and Molecular Physics
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All vibrations producing a change in the electric dipole moment of a molecule yield

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A piece of paraffin is placed in a uniform magnetic field H0. The sample contains hydrogen nuclei of mass mp, which interact only with external magnetic field. An additional oscillating magnetic field is applied to observe resonance absorption. If g1 is the g-factor of the hydrogen nucleus, the frequency at which resonance absorption takes place, is given by

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Consider the following statements about molecular spectra:
P. CH4 does not give pure rotational Raman lines
Q. SF6 could be studied by rotational Raman spectroscopy
R. N2 shows infrared absorption spectrum
S. CH3CH3 shows vibrational Raman and infrared absorption lines
T. H2O2 shows pure rotational spectrum
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The hyperfine structure of Na(32P3/2) with nuclear = 3/2 has

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The number of hyperfine components observed in the electronic transition  of an atom with nuclear spin is

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The spectral term for the atom with 70% filled subshell and only s = is

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A system has energy level E0, 2E0, 3E0, . . . . . , where the excited states are triply degenerated. Four non-interacting bosons are placed in this system. If the total energy of these bosons is 5E0, the number of microstates is

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The far infrared rotational absorption spectrum of a diatomic molecule shows equidistant lines with spacing 20 cm-1. The position of the first stokes line in the rotational Raman spectrum of this molecule is

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The three principal moments of inertia of a methanol (CH3OH) molecule have the property   and  The rotational energy eigenvalues are

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The total number of Zeeman components observed in an electronic transition  of an atom in a weak field is

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The number of fundamental vibrational modes of CO2 molecule is

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The spectrum of radiation emitted by a black body at a temperature 1000 K peaks in the

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In a diatomic molecule, the inter-nuclear separation of the ground and first excited electronic state are the same as shown in the figure. If the molecule is initially in the lowest vibrational state of the ground state, then the absorption spectrum will appear as
Atomic and Molecular Physics mcq question image

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The Lande g-factor for the level of an atom is

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A three-level system of atoms has N1 atoms in level E1, N2 in level E2 and N3 in level E3 (N2 > N1 > N3 and E1 < E2 < E3). Lasere mission is possible between the levels

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The principal series of spectral lines of lithium is obtained by transitions between

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An atom with one outer electron having orbital angular momentum is placed in a weak magnetic field. The number of energy levels into which the higher total angular momentum state splits, is

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In a He-Ne laser, the laser transition takes place in

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Which one of the following electronic transitions in neon is not responsible for LASER action in a helium-neon laser?

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The spin-orbit coupling constant for the upper state of sodium atom which emits D lines of wave numbers 16956.2 and 16973.4 cm-1 is

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