If the partition function of a harmonic oscillator with frequency ω at a temperature T is ℏωkT, then the free energy of N such independent oscillators is
Consider black body radiation in a cavity maintained at 2000 K. If the volume of the cavity is reversibly and adiabatically increased from 10 cm3 to 640 cm3, the temperature of the cavity changes to
Consider a system of N atoms of an ideal gas of type A at temperature T and volume V. It is kept in diffusive contact with another system of N atoms of another ideal gas of type B at the same temperature T and volume V. Once the combined system reaches equilibrium,
The internal energy of n moles of a gas is given E=23nRT−Va, where V is the volume of the gas at temperature T and a is a positive constant. One mole of the gas in state (T1, V1) is allowed to expand adiabatically into vacuum to a final state (T2, V2). The temperature T2 is
Consider a system of two non-interacting classical particles which can occupy any of the three energy levels with energy values E = 0, ε and 2ε having degeneracies g(E) = 1, 2 and 4 respectively, The mean energy of the system is
The number of states for a system of N identical free particles in a three-dimensional space having total energy between E and E + δE (δE ≪ E), is proportional to the
Two identical particles have to be distributed among three energy levels. Let rB, rF and rC represent the ratios of probability of finding two particles to that of finding one particle in a given energy state. The subscripts B, F and C correspond to whether the particles are Bosons, Fermions and classical particles, respectively. The rB : rF : rC is equal to
Thermodynamic variables of a system can be volume V, pressure p, temperature T, number of particles N, internal energy E and chemical potential μ, etc. For a system to be specified by Microcanonical (MC), Canonical Ensemble (CE) and Grand Canonical (GC) ensembles, the parameters required for the respective ensembles are
The free energy of a photon gas enclosed in a volume V is given by F=−31aVT−4, where a is a constant and T is the temperature of the gas. The chemical potential of the photon gas is
A sample of ideal gas with initial pressure p and volume V is taken through an isothermal expansion proceed during which the change in entropy is found to be ΔS. The universal gas constant is R. Then the work done by the gas is given by