The formulae for change in entropy
A. Δ S = R l n ( V 1 V 2 ) = − R ln ( P 1 P 2 ) ,
B. Δ S = C P ln ( T 1 T 2 ) ,
C. Δ S = C V ln ( T 1 T 2 ) ,
D. All are correct
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Critical value of the Gibbs energy of nucleation at equilibrium temperature is
A. zero
B. Infinite
C. positive
D. negative
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The constant term "2" in mathematical expression for phase rule is stands for
A. temperature
B. pressure
C. number of phases
D. both A and B
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Consider a reaction with activation energy of 8.314 kJ/mol that takes place at 300 K. If the reaction rate is to be tripled, the temperature of the reaction should be
A. 174.5 K
B. 447.5 K
C. 600.5 K
D. 847.5 K
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During the reduction of an oxide of hydrogen gas, it is observed that the rate of reaction increases by almost three fold due to a slight increases in temperature. The most likely rate controlling step is
A. inward mass transfer of hydrogen gas
B. outward mass transfer of H2 O
C. chemical reaction at gas metal interface
D. combined mass transfer of H2 and H2 O
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The chemical potential of a component 1 in a solution is given by, μi =
A. ( δ n 1 δ E ) T , P , n 2 , n 3 ...
B. ( δ n 1 δ H ) S , V , n 2 , n 3 ...
C. ( δ n 1 δ A ) T , V , n 2 , n 3 ...
D. ( δ n 1 δ G ) P , V , n 2 , n 3 ...
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Isothermal compressibility of a material is given by
A. − P 1 ( ∂ P ∂ V ) T
B. P 1 ( ∂ P ∂ V ) T
C. − V 1 ( ∂ P ∂ V ) T
D. V 1 ( ∂ P ∂ V ) T
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The process in which all small steps are in equilibrium, so that entire process is in equilibrium is
A. adiabatic isothermal process
B. isothermal process
C. quasi-static process
D. isobaric process
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pure nickel melts at 1726K at 105 Pa (1 atm.) pressure, ΔV (solid-liquid) = 0.26 × 10-6 m3 . mol-1 and the heat of fusion, ΔHf = 18000 J.mol-1 . The melting point of pure nickel, when acted upon by a pressure of 108 Pa is . . . . . . . . K.
A. 1701.5
B. 1723.5
C. 1728.5
D. 1751. 5
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What will be the degree of freedom for single phase system of binary system?
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Which one of the following is not an intensive property?
A. temperature
B. pressure
C. volume
D. refractive index
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Activation energy of a chemical reaction, homogeneous or heterogeneous, is graphically estimated from a plot between
A. K versus T
B. k 1 versus T
C. k 1 versus In T
D. In k versus T 1
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2cu(s) + 0.5 O2 (g) = Cu2 O(s);
ΔG° = - 162200 + 69.24 T, J
2Cu(l) + 0.5 O2 (g) = CU2 O(s);
ΔG° = - 1188300 + 88.48 T, J
The molar free energy/change at 1300 K for the transformation of solid Cu to liquid Cu will be . . . . . . . . J.
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Which of the following partial derivative is equal to ( ∂ P ∂ S ) T ?
A. − ( ∂ T ∂ V ) P
B. − ( ∂ V ∂ S ) T
C. ( ∂ T ∂ V ) S
D. − ( ∂ V ∂ S )
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Heat capacity at constant pressure is defined by
A. ( ∂ T ∂ E ) p
B. ( ∂ T ∂ G ) e
C. ( ∂ T ∂ H ) p
D. ( ∂ T ∂ ( E + P v ) ) p
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In thermodynamics, the law of conservation of energy is expressed in the form of
A. zeroth law of thermodynamics
B. first law of thermodynamics
C. second law of thermodynamics
D. third law of thermodynamics
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Which of the following phase will have lowest entropy
A. solid
B. liquid
C. gas
D. none of these
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The first law of thermodynamics can be stated as:
A. dE = δQ - δW
B. dQ = dE - δW
C. δW = dQ + dE
D. dW = δQ - δE
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Integral enthalpy of mixing (in J/mol) of liquid (Cu, Zn) solution can be approximated by ΔHm mix = - 19250 XCu XZn
The corresponding partial molar enthalpy of mixing (in J/mol) for Cu is
A. 19250x2 zn
B. - 19250x2 cu
C. 38500xzn - 19250x2 zn - 19250
D. - 19250 x2 zn
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The sequence of processes which return back to its initial point is called
A. adiabatic process
B. isothermal process
C. cyclic process
D. isobaric process
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