Pick out the wrong statement pertaining to the decomposition of PCl5 represented by, PCl5 ⇋ PCl3 + Cl2 . Degree of dissociation of PCl5 will
A. Decrease on addition of Cl2
B. Increase on addition of an inert gas at constant pressure
C. Decrease on increasing the pressure of the system
D. None of these
Select an option to see the answer and solution.
A gas mixture of three components is brought in contact with a dispersion of an organic phase in water. The degree of freedom of the system are
Select an option to see the answer and solution.
The compressibility factor of a gas is given by (where, V1 = actual volume of the gas V2 = gas volume predicted by ideal gas law)
A. V 2 V 1
B. V 1 V 2
C. V1 - V2
D. V1 × V2
Select an option to see the answer and solution.
Air enters an adiabatic compressor at 300 K. The exit temperature for a compression ratio of 3, assuming air to be an ideal gas ( γ = C v C p = 5 7 ) and the process to be reversible, is
A. 300 ( 3 7 2 )
B. 300 ( 3 5 3 )
C. 300 ( 3 7 3 )
D. 300 ( 3 7 5 )
Select an option to see the answer and solution.
As the temperature is lowered towards the absolute zero, the value of the quantity ( ∂ T ∂ Δ F ) approaches
A. Zero
B. Unity
C. Infinity
D. None of these
Select an option to see the answer and solution.
Refrigeration capacity of a household refrigerator may be round about __________ tons.
Select an option to see the answer and solution.
All gases during throttling process at atmospheric temperature and pressure show a cooling effect except
Select an option to see the answer and solution.
On opening the door of an operating refrigerator kept in a closed room, the temperature of the room will
A. Increase
B. Decrease
C. Remain same
D. Increase in summer and will decrease in winter
Select an option to see the answer and solution.
The value of gas constant 'R' is
A. 1.987 cal/gm mole °K
B. 1.987 BTU/lb. mole °R
C. Both A and B
D. Neither A nor B
Select an option to see the answer and solution.
With increase in pressure (above atmospheric pressure), the Cp of a gas
A. Increases
B. Decreases
C. Remains unchanged
D. First decreases and then increases
Select an option to see the answer and solution.
The unit of equilibrium constant of a chemical reaction is the same as that of
A. Molar concentration
B. Temperature
C. Internal energy
D. None of these
Select an option to see the answer and solution.
Compressibility factor (i.e., the ratio of actual volume of gas to the volume predicted by ideal gas law) for all gases are
A. Always greater than one
B. Same at the same reduced temperature
C. Same at the same reduced pressure
D. Both B & C
Select an option to see the answer and solution.
During a reversible isothermal expansion of an ideal gas, the entropy change is
Select an option to see the answer and solution.
When a gas in a vessel expands, its internal energy decreases. The process involved is
A. Reversible
B. Irreversible
C. Isothermal
D. Adiabatic
Select an option to see the answer and solution.
Minimum number of phases that exists in a system is 1. Number of chemical species in a colloidal system is
Select an option to see the answer and solution.
Which of the following is not affected by temperature changes?
A. Fugacity
B. Activity co-efficient
C. Free energy
D. None of these
Select an option to see the answer and solution.
Forward reaction will be favoured for the exothermic reaction, represented by CO + H2 O ⇋ CO2 + H2 , by
A. Low temperature and high pressure
B. Low temperature and low pressure
C. High temperature and high pressure
D. High temperature and low pressure
Select an option to see the answer and solution.
The principle applied in liquefaction of gases is
A. Adiabatic expansion
B. Joule-Thomson effect
C. Both A and B
D. Neither A nor B
Select an option to see the answer and solution.
For a cyclic process, a fixed ratio between heat and work
A. Always exists
B. May exist
C. Never exists
D. Is difficult to predict
Select an option to see the answer and solution.
The temperature at which a real gas obeys the ideal gas laws over a wide range of pressure is called the __________ temperature.
A. Critical
B. Boyle
C. Inversion
D. Reduced
Select an option to see the answer and solution.