P V γ = Constant (where, γ = C v C p ) is valid for a/an __________ process.
A. Isothermal
B. Isentropic
C. Isobaric
D. Adiabatic
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In the reaction, represented by, 2SO2 + O2 ⇋ 2SO3 ; ΔH = -42 kcal; the forward reaction will be favoured by
A. Low temperature
B. High pressure
C. Both A and B
D. Neither A nor B
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Trouton's ratio of __________ liquids is calculated using Kistyakowsky equation.
A. Polar
B. Non-polar
C. Both A & B
D. Neither A nor B
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The heat capacities for the ideal gas state depend upon the
A. Pressure
B. Temperature
C. Both A & B
D. Neither A nor B
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An ideal liquid refrigerant should
A. Not have a subatmospheric vapour pressure at the temperature in the refrigerator coils
B. Not have unduly high vapour pressure at the condenser temperature
C. Both A and B
D. Have low specific heat
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One mole of nitrogen at 8 bar and 600 K is contained in a piston-cylinder arrangement. It is brought to 1 bar isothermally against a resisting pressure of 1 bar. The work done (in Joules) by the gas is
A. 30554
B. 10373
C. 4988.4
D. 4364.9
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Dry ice is
A. Moisture free ice
B. Solid helium
C. Solid carbon dioxide
D. None of these
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Compressibility factor-reduced pressure plot on reduced co-ordinates facilitates
A. Use of only one graph for all gases
B. Covering of wide range
C. Easier plotting
D. More accurate plotting
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Entropy of a substance remains constant during a/an __________ change.
A. Reversible isothermal
B. Irreversible isothermal
C. Reversible adiabatic
D. None of these
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Which of the following is a thermodynamic property of a system?
A. Concentration
B. Mass
C. Temperature
D. Entropy
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Third law of thermodynamics is concerned with the
A. Value of absolute entropy
B. Energy transfer
C. Direction of energy transfer
D. None of these
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Second law of thermodynamics is concerned with the
A. Amount of energy transferred
B. Direction of energy transfer
C. Irreversible processes only
D. Non-cyclic processes only
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Those solutions in which there is no volume change upon mixing the components in the liquid state and which, when diluted do not undergo any heat change (i.e. heat of dilution is zero), are called __________ solutions.
A. Ideal
B. Real
C. Isotonic
D. None of these
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Internal energy change of a system over one complete cycle in a cyclic process is
A. Zero
B. +ve
C. -ve
D. Dependent on the path
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Two substances are in equilibrium in a reversible chemical reaction. If the concentration of each substance is doubled, then the value of the equilibrium constant will be
A. Same
B. Doubled
C. Halved
D. One fourth of its original value
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Work done in case of free expansion is
A. Indeterminate
B. Zero
C. Negative
D. None of these
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Critical solution temperature (or the con-solute temperature) for partially miscible liquids (e.g., phenol-water) is the minimum temperature at which
A. A homogeneous solution (say of phenol water) is formed
B. Mutual solubility of the two liquids shows a decreasing trend
C. Two liquids are completely separated into two layers
D. None of these
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In which of the following reaction equilibria, the value of equilibrium constant Kp will be more than is Kc ?
A. 2HI ⇋ H2 + I 2
B. N2 O4 ⇋ 2NO2
C. 2SO2 + O2 ⇋ 2SO3
D. None of these
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As the temperature is lowered towards the absolute zero, the value of ( ∂ T ∂ Δ F ) , then approaches
A. Unity
B. Zero
C. That of the heat of reaction
D. Infinity
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Reduced pressure of a gas is the ratio of its
A. Pressure to critical pressure
B. Critical pressure to pressure
C. Pressure to pseudocritical pressure
D. Pseudocritical pressure to pressure
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